Kevlar

Kevlar is synthesised from the monomers 1,4-phenylene-diamine (para-phenylenediamine) and terephthaloyl chloride in condensation reaction yielding hydrochloric acid as a byproduct. The result is a liquid-crystalline behaviour and mechanical drawing orienting the polymer chains in the fibre's direction.

Fibers of Kevlar consist of long molecular chains produced from PPTA (poly-paraphenylene terephthalamide). There are many inter-chain bonds making the material extremely strong. Kevlar derives part of its high strength from inter-molecular hydrogen bonds formed between the carbonyl groups and protons on neighboring polymer chains and the partial pi stacking of the benzenoid aromatic stacking interactions between stacked strands.

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There are two articles about Kevlar; Monnerie1977 and Northolt1974

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A list of all molecule examples in these pages.

by Maria Pinjanainen, Laboratory of Polymer Technology